Definitely one of their Raw matches sticks out in my memory as being great heavyweight wrestling; I think it was the night after a PPV 5-way and it just showed some great heavy lifting that made Reigns seem more credible than most of his opponents could do.
I honestly do not remember them having a PPV match, but I'm suddenly reminded of Joe's PPV match with Kofi, where Kofi won with a Trouble In Paradise out of nowhere and neither Joe nor Kofi got to tell any sort of story. Joe was overcoming that awful night nicely when he and Aleister Black were taking on Seth and Murphy (can't remember who else was involved) before Joe got injured. His character at that point was great as it ever was and I kinda wonder if he'll ever be as interesting as when he was going against the odds (from a booking perspective, i mean)...